For the oxidation of a tertiary amine by reagents such as hydrogen peroxide, \(\ce{H_2O_2}\), or peroxycarboxylic acids, \(\ce{RCOOOH}\), which can supply an oxygen atom with six electrons, the expected product is an azane oxide (amine oxide). K. Bahrami, M. …
O'Sullivan J(1), Davey G, O'Sullivan M, Tipton KF. The hydrogen peroxide-zirconium(IV) chloride reagent system is efficient and general for the conversion of thioamides to amides in short reaction times and good chemoselectivity, and allows a simple workup that precludes the use of toxic solvents. Hydrogen peroxide is a chemical compound with the formula H 2 O 2.In its pure form, it is a very pale blue liquid, slightly more viscous than water.Hydrogen peroxide is the simplest peroxide (a compound with an oxygen–oxygen single bond).It is used as an oxidizer, bleaching agent, and antiseptic.Concentrated hydrogen peroxide, or "high-test peroxide", is a reactive oxygen species …
amine, and a reagent which will convert cobalt(II) to cobalt(III). hydrogen peroxide as an oxidant in organic react ions is the unavoidable presence of water as the solvent of the commerci al hydrogen peroxid e and reduction products. Reactions of Amines (continued) 4. Because of the low covalent bond energy of the peroxide bond (ca.35 kcal/mole), these compounds are widely ... the beta-hydrogen and amine oxide moieties necessarily have a syn-relationship. To take back the white colour, hydrogen peroxide is reacted with lead sulfide. A variety of hydrogen peroxide-derived systems for amine oxidation were investigated.
A process for alkaline hydrogen peroxide bleaching of mechanical wood pulp which employs a quaternary amine compound, such as (3-chloro-2-hydroxypropyl)trimethyl ammonium chloride, in the stabilized bleach solution. The Journal of Physical Chemistry A 2007, 111 (16) , 3152-3160. This reaction can be catalyzed by minute traces of transition metal ions.
The product of this reaction is a 30舑40% solution of the amine oxide. K. Bahrami, M. …
A closely related mechanism for the H2O2 …
The hydrogen peroxide-zirconium(IV) chloride reagent system is efficient and general for the conversion of thioamides to amides in short reaction times and good chemoselectivity, and allows a simple workup that precludes the use of toxic solvents. The preferred reaction uses hydrogen peroxide as oxidant and water as the reaction medium. Oxides of tertiary amines, such as dimethyldodecylamine oxide, are known to be useful as detergents and foam stabilizers, and are now in commerical use. They are therefore important intermediates for chemical syntheses.
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